Published in
Royal Society of Chemistry, Chemical Communications, 65(54), p. 8960-8963
DOI: 10.1039/c8cc04298e
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Dual role of ethyl bromodifluoroacetate in the formation of fluorine-containing heteroaromatic compounds
Journal article published in 2018 by
Xingxing Ma,
Shaoyu Mai,
Yao Zhou 
,
Gui-Juan Cheng ,
Qiuling Song
,
Gui-Juan Cheng ,
Qiuling Song
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Abstract
An efficient one-pot cascade process via unprecedented quadruple cleavage of BrCF2COOEt with primary amines to afford valuable fluorine-containing heterocycles is described, in which BrCF2COOEt plays a dual role as a C1 synthon and a difluoroalkylating reagent for the first time.