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Royal Society of Chemistry, Dalton Transactions, 39(46), p. 13544-13552, 2017

DOI: 10.1039/c7dt03084c

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[TcII(NO)(trifluoroacetate)4F]2− – synthesis and reactions

Journal article published in 2017 by S. M. Balasekaran ORCID, A. Hagenbach, M. Drees ORCID, U. Abram ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Cs(NBu4)[Tc(NO)(OOCCF3)4F] can act as a precursor for the synthesis of further Tc(ii) and Tc(i) nitrosyl complexes with trifluoroacetato or fluorido ligands. The Tc(i) compounds show unusual99Tc NMR chemical shifts.