Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 26(19), p. 17028-17035
DOI: 10.1039/c7cp02758c
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Laser photolysis studies of ω-bond dissociation in aromatic carbonyls with a C–C triple bond stimulated by triplet sensitization
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Abstract
We have prepared three types of carbonyl compounds, benzoylethynylmethyl phenyl sulfide (2@SPh), (p-benzoyl)phenylethynylmethyl phenyl sulfide (3@SPh) andp-(benzoylethynyl)benzyl phenyl sulfide (4@SPh) with benzoyl and phenylthiylmethyl groups, which are interconnected with a C–C triple bond and a phenyl ring.