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Royal Society of Chemistry, Green Chemistry, 1(19), p. 270-280

DOI: 10.1039/c6gc02366e

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A promising low pressure methanol synthesis route from CO2 hydrogenation over Pd@Zn core–shell catalysts

Journal article published in 2017 by Fenglin Liao, Xin-Ping Wu ORCID, Jianwei Zheng, Molly Meng-Jung Li ORCID, Anna Kroner, Ziyan Zeng, Xinlin Hong, Youzhu Yuan, Xue-Qing Gong, Shik Chi Edman Tsang
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

We report a new Pd@Zn core–shell catalyst that offers a significantly higher kinetic barrier to CO/H2O formation in CO2 hydrogenation but facilitates CH3OH production at below 2 MPa with CH3OH selectivity at 70% as compared to 10% over Cu catalysts.