Published in
Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 3(6), p. 654-660
DOI: 10.1039/c7tc04661h
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The contraction of PEDOT films formed on a macromolecular liquid-like surface
Journal article published in 2018 by
Liangqi Ouyang 
,
Mohammad J. Jafari ,
Wanzhu Cai,
Luis Ever Aguirre,
Chuanfei Wang ,
Thomas Ederth ,
Olle Inganäs
,
Mohammad J. Jafari ,
Wanzhu Cai,
Luis Ever Aguirre,
Chuanfei Wang ,
Thomas Ederth ,
Olle Inganäs
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Abstract
Vapour phase polymerized PEDOT on the oxidizer layer adopts a neutral benzenoid structure. After solvent rinsing, the polymer chain is deprotonated and rearranged, giving rise to doped quinoid structure and partly contributing to the contraction of the film.