Published in
Royal Society of Chemistry, Dalton Transactions, 39(46), p. 13364-13375
DOI: 10.1039/c7dt02534c
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Flexibility and lability of a phenyl ligand in hetero-organometallic 3d metal–Sn(iv) compounds and their catalytic activity in Baeyer–Villiger oxidation of cyclohexanone
Journal article published in 2017 by
Susanta Hazra 
,
Nuno M. R. Martins ,
Maxim L. Kuznetsov ,
M. Fátima C. Guedes da Silva ,
Armando J. L. Pombeiro
,
Nuno M. R. Martins ,
Maxim L. Kuznetsov ,
M. Fátima C. Guedes da Silva ,
Armando J. L. Pombeiro
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Abstract
An intermetallic Ph-shift (SnIV-to-CoIII) leads to a CoIII(Ph)–SnIV(Ph) and a mononuclear CoIII(Ph) compounds, while a M⋯π(Ph) interaction in the NiII/CuII–SnIV systems represents an intermediate stage of that Ph-shift.