Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 14(5), p. 2171-2178, 2018
DOI: 10.1039/c8qo00429c
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Searching for original natural products by molecular networking: detection, isolation and total synthesis of chloroaustralasines
Journal article published in 2018 by
F. Olivon 
,
C. Apel ,
P. Retailleau ,
P. M. Allard ,
J. L. Wolfender ,
D. Touboul ,
F. Roussi ,
M. Litaudon ,
S. Desrat
,
C. Apel ,
P. Retailleau ,
P. M. Allard ,
J. L. Wolfender ,
D. Touboul ,
F. Roussi ,
M. Litaudon ,
S. Desrat
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Abstract
Four unprecedented chlorinated monoterpenyl quinolones have been isolated using a molecular networking based prioritisation strategy. The bio-inspired total synthesis of chloroaustralasine A involving a chloroperoxydase-mediated hydroxychlorination is described.