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Royal Society of Chemistry, Dalton Transactions, 27(47), p. 8892-8896

DOI: 10.1039/c8dt01455h

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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

Journal article published in 2018 by Masaichi Saito ORCID, Naoki Matsunaga, Jumpei Hamada, Shunsuke Furukawa ORCID, Mao Minoura, Susann Wegner, Juri Barthel ORCID, Christoph Janiak ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes.