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Royal Society of Chemistry, Dalton Transactions, 37(45), p. 14719-14724

DOI: 10.1039/c6dt01648k

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Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile

Journal article published in 2016 by Marte Sofie Martinsen Holmsen, Ainara Nova ORCID, David Balcells ORCID, Eirin Langseth, Sigurd Øien-Ødegaard, Eline Aasen Tråseth, Richard H. Heyn, Mats Tilset
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Incorporation of the simple, readily available, building blocks ethylene, water and acetonitrile into Au(tpy)(OCOCF3)2 (tpy = 2-(p-tolyl)pyridine) in a one-step reaction leads to high yields of a new 6-membered ring gold(iii) metallacycle complex.