Published in
Royal Society of Chemistry, Dalton Transactions, 37(45), p. 14719-14724
DOI: 10.1039/c6dt01648k
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Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile
Journal article published in 2016 by
Marte Sofie Martinsen Holmsen,
Ainara Nova 
,
David Balcells ,
Eirin Langseth,
Sigurd Øien-Ødegaard,
Eline Aasen Tråseth,
Richard H. Heyn,
Mats Tilset
,
David Balcells ,
Eirin Langseth,
Sigurd Øien-Ødegaard,
Eline Aasen Tråseth,
Richard H. Heyn,
Mats Tilset
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Abstract
Incorporation of the simple, readily available, building blocks ethylene, water and acetonitrile into Au(tpy)(OCOCF3)2 (tpy = 2-(p-tolyl)pyridine) in a one-step reaction leads to high yields of a new 6-membered ring gold(iii) metallacycle complex.