Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 11(5), p. 5442-5448
DOI: 10.1039/c6ta10818k
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Suppressing the chromium disproportionation reaction in O3-type layered cathode materials for high capacity sodium-ion batteries
Journal article published in 2017 by
Ming-Hui Cao,
Yong Wang,
Zulipiya Shadike,
Ji-Li Yue,
Enyuan Hu,
Seong-Min Bak 
,
Yong-Ning Zhou,
Xiao-Qing Yang,
Zheng-Wen Fu
,
Yong-Ning Zhou,
Xiao-Qing Yang,
Zheng-Wen Fu
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Abstract
The reversible multi-electron oxidation/reduction process of Cr3+/Cr4.2+ with a large reversible capacity can be achieved in a novel O3-type NaCr1/3Fe1/3Mn1/3O2. The disproportionation reaction of Cr4+ to Cr3+ and Cr6+ can be effectively suppressed by Fe3+ and Mn4+ substitution.