Published in
Royal Society of Chemistry, Chemical Communications, 48(54), p. 6173-6176
DOI: 10.1039/c8cc02035c
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Combining a pyclen framework with conjugated antenna for the design of europium and samarium luminescent bioprobes
Journal article published in 2018 by
Nadège Hamon,
Margaux Galland,
Mariane Le Fur,
Amandine Roux,
Alain Duperray 
,
Alexei Grichine ,
Chantal Andraud,
Boris Le Guennic ,
Maryline Beyler,
Olivier Maury ,
Raphaël Tripier
,
Alexei Grichine ,
Chantal Andraud,
Boris Le Guennic ,
Maryline Beyler,
Olivier Maury ,
Raphaël Tripier
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Abstract
The first pyclen based ligand bearing two picolinate intra-ligand charge transfer transition antennae and one acetate arm organized in a dissymmetric manner was synthesized for Eu(III) and Sm(III) complexation. The europium complex presents an excellent brightness and biphotonic imaging of T24-cells has been performed using Eu(III) and the less common Sm(III) bioprobes.