Published in
Royal Society of Chemistry, Catalysis Science & Technology, 24(6), p. 8548-8561
DOI: 10.1039/c6cy01884j
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Mechanistic insight into the pyridine enhanced α-selectivity in alkyne hydrothiolation catalysed by quinolinolate–rhodium(i)–N-heterocyclic carbene complexes
Journal article published in 2016 by
Laura Palacios,
Andrea Di Giuseppe 
,
María José Artigas,
Victor Polo,
Fernando J. Lahoz,
Ricardo Castarlenas,
Jesús J. Pérez-Torrente ,
Luis A. Oro
,
María José Artigas,
Victor Polo,
Fernando J. Lahoz,
Ricardo Castarlenas,
Jesús J. Pérez-Torrente ,
Luis A. Oro
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Abstract
Highly Markovnikov-selective RhI–NHC–quinolinolate catalysts in alkyne hydrothiolation are reported.