Published in
Royal Society of Chemistry, Dalton Transactions, 45(46), p. 15865-15874
DOI: 10.1039/c7dt03327c
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Half-sandwich complexes of Ir(iii), Rh(iii) and Ru(ii) with the MaxPhos ligand: metal centred chirality and cyclometallation
Journal article published in 2017 by
Juan Téllez,
Albert Gallen 
,
Joaquina Ferrer ,
Fernando J. Lahoz ,
Pilar García-Orduña ,
Antoni Riera ,
Xavier Verdaguer ,
Daniel Carmona ,
Arnald Grabulosa
,
Joaquina Ferrer ,
Fernando J. Lahoz ,
Pilar García-Orduña ,
Antoni Riera ,
Xavier Verdaguer ,
Daniel Carmona ,
Arnald Grabulosa
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Abstract
The MaxPhos ligand forms half-sandwich Rh, Ir and Ru complexes diastereoselectively. The Ir complex cyclometallates through C(sp3)–H activation.