Published in
Royal Society of Chemistry, New Journal of Chemistry, 11(42), p. 8693-8703
DOI: 10.1039/c8nj01018h
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Mechanism of generation of closo-decaborato amidrazones. Intramolecular non-covalent B–H⋯π(Ph) interaction determines stabilization of the configuration around the amidrazone CN bond
Journal article published in 2018 by
Valeria K. Burianova 
,
Dmitrii S. Bolotin ,
Alexander S. Mikherdov ,
Alexander S. Novikov ,
Pennie Petrus Mokolokolo,
Andreas Roodt ,
Vadim P. Boyarskiy ,
Dmitry Dar’in,
Mikhail Krasavin,
Vitalii V. Suslonov ,
Andrey P. Zhdanov ,
Konstantin Y.-U. Zhizhin,
Nikolay T. Kuznetsov
,
Dmitrii S. Bolotin ,
Alexander S. Mikherdov ,
Alexander S. Novikov ,
Pennie Petrus Mokolokolo,
Andreas Roodt ,
Vadim P. Boyarskiy ,
Dmitry Dar’in,
Mikhail Krasavin,
Vitalii V. Suslonov ,
Andrey P. Zhdanov ,
Konstantin Y.-U. Zhizhin,
Nikolay T. Kuznetsov
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Abstract
Three types of N(H)-nucleophiles were used to study the nucleophilic addition to the CN group of the 2-propanenitrilium closo-decaborate cluster giving N-closo-decaborato amidrazones.