Published in
Royal Society of Chemistry, Dalton Transactions, 43(46), p. 14957-14972
DOI: 10.1039/c7dt02420g
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Dihydrobis(methimazolyl)borato complexes of ruthenium and osmium
Journal article published in 2017 by
Mark R. St.-J. Foreman 
,
Chenxi Ma,
Anthony F. Hill ,
Natalie E. Otten,
Manab Sharma,
Never Tshabang,
Jas S. Ward
,
Chenxi Ma,
Anthony F. Hill ,
Natalie E. Otten,
Manab Sharma,
Never Tshabang,
Jas S. Ward
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Abstract
The reaction of Na[H2B(mt)2] (mt = 2-mercapto, 3-methylimidazol-1-yl, methimazolyl) with [Ru(X)Cl(CO)(PPh3)n] (n= 3 X = H;n= 2 BO2C6H4, SiCl3, SiMe3) affords the complexes [Ru(X)(CO)(PPh3){κ2-H,S,S′-H2B(mt)2}].