Published in
Royal Society of Chemistry, Dalton Transactions, 1(47), p. 197-208
DOI: 10.1039/c7dt03939e
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Oxidoperoxidomolybdenum(vi) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties
Journal article published in 2018 by
Emilio Begines,
Carlos J. Carrasco 
,
Francisco Montilla ,
Eleuterio Álvarez ,
Fabio Marchetti ,
Riccardo Pettinari ,
Claudio Pettinari ,
Agustín Galindo
,
Francisco Montilla ,
Eleuterio Álvarez ,
Fabio Marchetti ,
Riccardo Pettinari ,
Claudio Pettinari ,
Agustín Galindo
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Abstract
Oxidoperoxido–molybdenum(vi) complexes Ph4P[Mo(O)(O2)2(QR)] and [Mo(O)(O2)(QR)2] (QR = acylpyrazolonate ligands) were synthesised and tested as catalysts in epoxidation, sulphoxidation and epoxide deoxygenation.