Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 21(19), p. 13515-13523, 2017
DOI: 10.1039/c7cp01008g
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Formic acid catalyzed isomerization of protonated cytosine: a lower barrier reaction for tautomer production of potential biological importance
Journal article published in 2017 by
Lingxia Jin 
,
Mengdan Lv,
Mengting Zhao,
Rui Wang,
Caibin Zhao,
Jiufu Lu,
Ling Wang,
Wenliang Wang ,
Yawen Wei
,
Mengdan Lv,
Mengting Zhao,
Rui Wang,
Caibin Zhao,
Jiufu Lu,
Ling Wang,
Wenliang Wang ,
Yawen Wei
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Abstract
Isomerization barrier for isolated unimolecular reaction is quite high, and its probability may be very small. Reduction of isomerization barrier is over 36 kJ mol−1in going from H2O to HCOOH⋯H2O group catalysts.