Published in
Royal Society of Chemistry, Chemical Communications, 27(53), p. 3854-3857
DOI: 10.1039/c7cc00865a
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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates
Journal article published in 2017 by
Asif Noor 
,
Jiawei Li,
George N. Khairallah,
Zhen Li,
Hossein Ghari,
Allan J. Canty ,
Alireza Ariafard ,
Paul S. Donnelly ,
Richard A. J. O'Hair
,
Jiawei Li,
George N. Khairallah,
Zhen Li,
Hossein Ghari,
Allan J. Canty ,
Alireza Ariafard ,
Paul S. Donnelly ,
Richard A. J. O'Hair
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Abstract
A palladium mediated synthesis of thioamides from aromatic carboxylic acids and substituted isothiocyanates was discovered by gas-phase experiments and theoretical studies.