Published in
Royal Society of Chemistry, New Journal of Chemistry, 4(42), p. 3035-3041
DOI: 10.1039/c7nj04275b
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Supported sub-nanometer Ta oxide clusters as model catalysts for the selective epoxidation of cyclooctene
Journal article published in 2018 by
G. Zwaschka,
M. Rondelli,
M. Krause,
M. D. Rötzer,
M. N. Hedhili 
,
U. Heiz,
J.-M. Basset ,
F. F. Schweinberger ,
V. D'Elia
,
U. Heiz,
J.-M. Basset ,
F. F. Schweinberger ,
V. D'Elia
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Abstract
The preparation of organic ligand-free, isolated and catalytically active tantalum oxide complexes (Ta1) and small clusters (Tan>1) on flat silicate support was accomplished by ultra-high vacuum (UHV) techniques followed by oxidation in air.