Published in
Royal Society of Chemistry, Journal of Materials Chemistry C Materials for optical and electronic devices, 14(6), p. 3757-3761
DOI: 10.1039/c7tc05775j
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Oxidation of rubrene, and implications for device stability
Journal article published in 2018 by
Jack T. Ly,
Steven A. Lopez 
,
Janice B. Lin ,
Jae Joon Kim ,
Hyunbok Lee ,
Edmund K. Burnett,
Lei Zhang ,
Alán Aspuru-Guzik,
K. N. Houk ,
Alejandro L. Briseno
,
Janice B. Lin ,
Jae Joon Kim ,
Hyunbok Lee ,
Edmund K. Burnett,
Lei Zhang ,
Alán Aspuru-Guzik,
K. N. Houk ,
Alejandro L. Briseno
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Abstract
In studying the formation and thermally activated cycloreversion of oxidized rubrene to pristine rubrene, we observed an irreversible, second stage oxidized product. Understanding the formation of the irreversible adduct will help one design more chemically robust rubrene derivatives.