Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 27(14), p. 6479-6486
DOI: 10.1039/c6ob00918b
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Reactivity and selectivity of the reaction of O,O-diethyl 2,4-dinitrophenyl phosphate and thionophosphate with thiols of low molecular weight
Journal article published in 2016 by
J. G. Santos,
M. E. Aliaga,
K. Alarcón,
A. Torres,
D. Céspedes,
P. Pavez 
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Abstract
A kinetics control product by sulfhydryl attack of thiols was observed in the reactions of both triesters with Cys and Hcys, followed by an intramolecular amine attack leading to a thermodynamic control product.