Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 5(16), p. 825-831, 2018
DOI: 10.1039/c7ob02926h
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The unexpected racemization and hydrogen–deuterium exchange of the hydrogen at the α-carbon of proline analogs containing the 5-azoniaspiro[4.4]nonyl-group
Journal article published in 2018 by
B. Setner 
,
M. Wierzbicka ,
L. Jerzykiewicz ,
M. Lisowski ,
Z. Szewczuk
,
M. Wierzbicka ,
L. Jerzykiewicz ,
M. Lisowski ,
Z. Szewczuk
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Abstract
Herein, we present an unexpected racemization and the hydrogen–deuterium exchange (HDX) at the α-C atom of the proline derivative under basic aqueous conditions (1% water solution of triethylamine).