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Royal Society of Chemistry, Dalton Transactions, 1(47), p. 240-245

DOI: 10.1039/c7dt03830e

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A hydrogen-atom transfer mechanism in the oxidation of alcohols by [FeO4]2− in aqueous solution

Journal article published in 2018 by Jianhui Xie, Po-Kam Lo, Chow-Shing Lam, Kai-Chung Lau ORCID, Tai-Chu Lau ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The oxidation of alcohols by [FeO4]2− in aqueous solution is found to proceed via a hydrogen atom transfer (HAT) mechanism based on deuterium isotope effects, correlation between rate constants and bond dissociation energies (BDEs) and DFT calculations.