Manuel García Basallote
www2.uca.es
0000-0002-1802-8699
University of Cádiz
87 papers found
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Hydrogen and Copper Ion Induced Molecular Reorganizations in Two New Scorpiand-Like Ligands Appended with Pyridine Rings
The Role of Solvent on the Mechanism of Proton Transfer to Hydride Complexes: The Case of the [W3PdS4H3(dmpe)3(CO)]+Cubane Cluster
Structural reorganisation in polytopic receptors revealed by kinetic studies
Site specific ligand substitution in cubane-type Mo3FeS44+ clusters: Kinetics and mechanism of reaction and isolation of mixed ligand Cl/SPh complexes
Combined kinetic and DFT studies on the stabilization of the pyramidal form of H3PO2 at the heterometal site of [Mo3M’S4(H2O)10]4+ clusters (M’= Pd, Ni)
Dihydrogen complexes: striking effect of ion pairing to BF4− on the rotation of coordinated dihydrogen and the 19F relaxation time
Synthesis, Protonation and CuIIComplexes of Two Novel Isomeric Pentaazacyclophane Ligands: Potentiometric, DFT, Kinetic and AMP Recognition Studies
Mechanistic aspects of the chemistry of mononuclear CrIII complexes with pendant-arm macrocyclic ligands and formation of discrete CrIII/FeII and CrIII/FeII/CoIII cyano-bridged mixed valence compounds
Equilibrium and Kinetic Properties of CuII Cyclophane Complexes: The Effect of Changes in the Macrocyclic Cavity Caused by Changes in the Substitution at the Aromatic Ring
Sol–gel materials with trapped trinuclear class-II mixed-valence macrocyclic complexes that mimic their solution redox behaviour
Kinetic Study on Molecular Movements Induced by pH Gradients
Hydrogen and Copper Ion-Induced Molecular Reorganizations in Scorpionand-like Ligands. A Potentiometric, Mechanistic, and Solid-State Study
Catalytic effect of a second H3PO2in the mechanism of stabilisation of the unstable pyramidal tautomer of H3PO2coordinated at [Mo3S4M′] clusters (M′ = Ni, Pd)
The Structure of ([W3Q4X3(dmpe)3]+, Y-) Ion Pairs (Q = S, Se; X = H, OH, Br; Y = BF4, PF6, dmpe = Me2PCH2CH2PMe2) in Dichloromethane Solution and the Effect of Ion-Pairing on the Kinetics of Proton Transfer to the Hydride Cluster [W3S4H3(dmpe)3]+
Synthesis and Cu(II) coordination of two new hexaamines containing alternated propylenic and ethylenic chains: Kinetic studies on pH-driven metal ion slippage movements
New Insights into the Mechanism of Proton Transfer to Hydride Complexes: Kinetic and Theoretical Evidence Showing the Existence of Competitive Pathways for Protonation of the Cluster [W3S4H3(dmpe)3]+ with Acids
A combined stopped-flow, electrospray ionization mass spectrometry and31P NMR study on the acetic acid-mediated fragmentation of the hydroxo-chalcogenide cluster [W3Se4(OH)3(dmpe)3]+(dmpe = 1,2-bis(dimethylphosphanyl)ethane) to yield the dinuclear [W2Se2(µ-Se)2(µ-CH3CO2)(dmpe)2]+complex
Ag(i) complexes with alkylidene-bis(2-aminopyrimidines) as building units for discrete metallomacrocyclic frames. A structural and solution study
Mechanism of the Reaction of the[W3S4H3(dmpe)3]+ Cluster with Acids: Evidence for the Acid-Promoted Substitution of Coordinated Hydrides and the Effect of the Attacking Species on the Kinetics of Protonation of the Metal-Hydride Bonds
Mechanism of the Reaction of the [W3S4H 3(dmpe)3]+ Cluster with Acids: Evidence for the Acid-Promoted Substitution of Coordinated Hydrides and the Effect of the Attacking Species on the Kinetics of Protonation of the Metal-Hydride Bonds
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