Asuncion Barbero
0000-0001-6825-7775
University of Valladolid
65 papers found
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The regiochemistry of the stannylcupration of allenes: synthesis of allylstannanes using the lower order cuprate (Bu3Sn)CuCNLi
Allene: As small in size as versatile in synthesis. A general scope of its use-fulness as a C3-synthon for carbocyclic annulations
Acid-Catalyzed Cyclization of Epoxyallylsilanes. An Unusual Rearrangement Cyclization Process.
Addition of Organometallic Compounds to Tin-Containing Cyclic Ketones. Remote Stereocontrol Induced by the Stannyl Group.
Intramolecular Cyclization of tert -Butyldiphenylallylsilane Units and Carbonyl Groups: Allylsilane Terminated Cyclization versus the Ene Reaction
Remote Stereocontrol in Carbonyl Additions Promoted by Vinylstannanes
A tandem allylsilane–vinylsilane difunctionalization by silylcupration of allene followed by reaction with α,β-unsaturated nitriles
Allylsilane-vinylcopper reagents: Palladium-mediated coupling with alkenyl halides. Synthesis and photochemical [2+2] cyclization of (±)-Ipsdienol
Synthesis of Silyloxyvinylstannanes from BHT Ester Enolates and Stannyllithium Reagents. Copper(I)-Mediated Coupling with Alkenyl Halides
Functionalised Allylsilanes from Silylcopper Reagents and Allene. A Useful Strategy for Cyclopentane Annulations
The Peterson Olefination Using the tert-Butyldiphenylsilyl Group: Stereoselective Synthesis of Di- and Trisubstituted Alkenes
Silylcupration of allenes followed by reaction with enones. A new strategy for the synthesis of methylenecyclopentanols
Stannylcupration of Acetylenes Followed by Reaction with Epoxides: A Novel Annulation Strategy for the Synthesis of Cyclobutenes
Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds
Cycloaddition Reactions of (Z)-β-Siloxyacrylonitriles with Enones: Synthesis of 4H-Pyrans and Dihydro-2H-pyrans
In search of open-chain 1,3-stereocontrol
Open chain 1,3-stereocontrol
Synthesis of vinylsilanes by silyl-cupration of acetylenes using tert-butyldiphenylsilyl-cuprate reagents
Stannyl-cupration of acetylenes and the reaction of the intermediate cuprates with electrophiles as a synthesis of substituted vinylstannanes
Ring-formation from allyl- and vinylstannanes initiated by treatment with butyl-lithium
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