Massimo Bietti
0000-0001-5880-7614
79 papers found
Refreshing results…
Hydrogen atom transfer from tertiary alkanamides to the cumyloxyl radical. The role of substrate structure on alkali and alkaline earth metal ion induced C–H bond deactivation
Kinetic Study of the Reaction of the Phthalimide-N-oxyl Radical with Amides: Structural and Medium Effects on the Hydrogen Atom Transfer Reactivity and Selectivity
Fine Control over Site and Substrate Selectivity in Hydrogen Atom Transfer-Based Functionalization of Aliphatic C–H Bonds
A computational and experimental re-examination of the reaction of the benzyloxyl radical with DMSO
Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C–H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects
Binding to Redox-Inactive Alkali and Alkaline Earth Metal Ions Strongly Deactivates the C–H Bonds of Tertiary Amides toward Hydrogen Atom Transfer to Reactive Oxygen Centered Radicals
Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release: Equatorial C–H Activation vs Axial C–H Deactivation
Reactivity and Selectivity Patterns in Hydrogen Atom Transfer from Amino Acid C–H Bonds to the Cumyloxyl Radical: Polar Effects as a Rationale for the Preferential Reaction at Proline Residues
Kinetic Solvent Effects on the Reactions of the Cumyloxyl Radical with Tertiary Amides. Control over the Hydrogen Atom Transfer Reactivity and Selectivity through Solvent Polarity and Hydrogen Bonding
Reactions of the Cumyloxyl Radical with Secondary Amides. The Influence of Steric and Stereoelectronic Effects on the Hydrogen Atom Transfer Reactivity and Selectivity
Absolute Rate Constants for Hydrogen Atom Transfer from Tertiary Amides to the Cumyloxyl Radical: Evaluating the Role of Stereoelectronic Effects
Structural and Medium Effects on the Reactions of the Cumyloxyl Radical with Intramolecular Hydrogen Bonded Phenols. The Interplay Between Hydrogen-Bonding and Acid-Base Interactions on the Hydrogen Atom Transfer Reactivity and Selectivity
Reaction Pathways of Alkoxyl Radicals. The Role of Solvent Effects on C–C Bond Fragmentation and Hydrogen Atom Transfer Reactions
Importance of π-Stacking Interactions in the Hydrogen Atom Transfer Reactions from Activated Phenols to Short-LivedN-Oxyl Radicals
Reactions of the PhthalimideN-Oxyl Radical (PINO) with Activated Phenols: The Contribution of π-Stacking Interactions to Hydrogen Atom Transfer Rates
Tuning hydrogen atom abstraction from the aliphatic C–H bonds of basic substrates by protonation. Control over selectivity by C–H deactivation
Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding
Modeling noncovalent radical-molecule interactions using conventional density-functional theory: Beware erroneous charge transfer
Effect of metal ions on the reactions of the cumyloxyl radical with hydrogen atom donors. Fine control on hydrogen abstraction reactivity determined by Lewis acid-base interactions
Reactions of the Cumyloxyl and Benzyloxyl Radicals with Strong Hydrogen Bond Acceptors. Large Enhancements in Hydrogen Abstraction Reactivity Determined by Substrate/Radical Hydrogen Bonding
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