Sylvain Marque
0000-0002-3050-8468
141 papers found
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Alkoxyamine C–ON Bond Homolysis: Stereoelectronic Effects
Long-range polar and steric effects in propionate-SG1-type alkoxyamines (SG1-CHMeCOOX): a multiparameter analysis
2,5-dihydro-1H-imidazole-based nitroxides as prospective mediators in living radical polymerization.
Polystyrene-block-Poly(ethylene oxide) from Nitroxide Mediated Polymerization. Detection of Minor Species by Coupled Chromatographic Techniques.
Absolute rate constants for the addition of the 1-(tert-butoxy)carbonylethyl radical onto cyclic alkenes in solution.
Nitroxide bound β-cyclodextrin : is there an inclusion complex ?
Re-formation reaction of cyclic nitroxide-based alkoxyamines: steric and polar/stabilization effects.
Steric and Polar Effects of the Cyclic Nitroxyl Fragment on the C−ON Bond Homolysis Rate Constant
SG1 based alkoxyamines as radical initiators for the synthesis of lactones and lactames
Polar, Steric, and Stabilization Effects in Alkoxyamines C−ON Bond Homolysis: A Multiparameter Analysis
Reactivity of Phosphorus Centered Radicals
β-Fragmentation of alkoxyl radicals: Natural bond orbital analysis
Selective and efficient fluorination of chlorodiazines under solvent-free phase transfer catalysis
Factors Influencing C−ON Bond Homolysis in Alkoxyamines: Unexpected Behavior of SG1 ( N -(2-methyl-2-propyl)- N -(1-diethylphosphono-2,2-dimethylpropyl)- N -oxyl)-Based Alkoxyamines
Leveled Steric Effect in Alkoxyamines of SG1-Type
Evolution of the partition coefficients of peroxide initiators during the synthesis of high-impact polystyrene
Switched external magnetic field CIDNP studies of coupling reaction of carbon-centered radicals with TEMPO
Synthesis of a series of SG1 2-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxyl] based alkoxyamines, SG1-CH(Me)CO2R, and measurement of the homolysis rate constants of the C?ON bond
Diastereomeric excess upon cleavage and reformation of diastereomeric alkoxyamines
Long-Range Polar Effect on the C-ON Bond Homolysis in (tert-Butyl[1-(diethylphosphonyl)-2,2-dimethylpropyl]aminoxyl) SG1-Based Alkoxyamines
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