Sylvain Marque
0000-0002-3050-8468
146 papers found
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Persilylated Phosphoranyl Radicals: The First Persistent Noncyclic Phosphoranyl Radicals
Nitroxide-Mediated Polymerization: The Pivotal Role of thekdValue of the Initiating Alkoxyamine and the Importance of the Experimental Conditions
Nitroxide-Mediated Polymerization of Methyl Methacrylate Using an SG1-Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization
Crowded Phosphonylated Alkoxyamines with Low Dissociation Temperatures: A Milestone in Nitroxide-Mediated Polymerization
Laser Flash Photolysis and CIDNP Studies of Steric Effects on Coupling Rate Constants of Imidazolidine Nitroxide with Carbon-Centered Radicals, Methyl Isobutyrate-2-yl andtert-Butyl Propionate-2-yl⊥
Alkoxyamine C–ON Bond Homolysis: Stereoelectronic Effects
Long-range polar and steric effects in propionate-SG1-type alkoxyamines (SG1-CHMeCOOX): a multiparameter analysis
2,5-dihydro-1H-imidazole-based nitroxides as prospective mediators in living radical polymerization.
Polystyrene-block-Poly(ethylene oxide) from Nitroxide Mediated Polymerization. Detection of Minor Species by Coupled Chromatographic Techniques.
Absolute rate constants for the addition of the 1-(tert-butoxy)carbonylethyl radical onto cyclic alkenes in solution.
Nitroxide bound β-cyclodextrin : is there an inclusion complex ?
Re-formation reaction of cyclic nitroxide-based alkoxyamines: steric and polar/stabilization effects.
Steric and Polar Effects of the Cyclic Nitroxyl Fragment on the C−ON Bond Homolysis Rate Constant
SG1 based alkoxyamines as radical initiators for the synthesis of lactones and lactames
Polar, Steric, and Stabilization Effects in Alkoxyamines C−ON Bond Homolysis: A Multiparameter Analysis
Reactivity of Phosphorus Centered Radicals
β-Fragmentation of alkoxyl radicals: Natural bond orbital analysis
Selective and efficient fluorination of chlorodiazines under solvent-free phase transfer catalysis
Factors Influencing C−ON Bond Homolysis in Alkoxyamines: Unexpected Behavior of SG1 ( N -(2-methyl-2-propyl)- N -(1-diethylphosphono-2,2-dimethylpropyl)- N -oxyl)-Based Alkoxyamines
Leveled Steric Effect in Alkoxyamines of SG1-Type
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