This catalogue lists types of three ant subfamilies (Dolichoderinae, Formicinae and Martialinae) housed in the Formicidae Collection of the Hymenoptera Laboratory, Museu de Zoologia da Universidade de São Paulo (MZSP), Brazil. It provides label information, morphological condition of specimens, nomenclatural changes, and type status, following recommendations of the International Code of Zoological Nomenclature (ICZN). Here we present information on types of 101 nominal species, of which 96 are still valid. Eight species are only represented by holotypes, 27 species only by paratypes, seven by holotypes and paratypes, 56 species by syntypes, two species by paralectotypes and one species by a lectotype and paralectotypes. With this issue we complete the publication of information regarding all MZSP ant types, summing 4,741 specimens of 892 nomenclaturally valid species.