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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 1(65), p. m24-m24, 2008

DOI: 10.1107/s1600536808037963

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trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)

Journal article published in 2008 by Gerald O. Hunter, Matthias Zeller ORCID, Brian D. Leskiw
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethyl-hexane-2,4-dionate. The bis--β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octa-hedral with basically no distortion, and the methanol mol-ecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit are tilted by 18.64 (10)° against each other. O-H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100].