International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 6(68), p. o1655-o1656, 2012
DOI: 10.1107/s1600536812019356
Full text: Download
The benzohydrazide molecule of the title compound, C16H16N2O3·2H2O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, with the hydroxy- and ethoxy-substituted benzene rings. The dihedral angle between these benzene rings is 3.82 (7)°. The ethoxy group is almost coplanar with the attached benzene ring with a C—O—C—C torsion angle of −176.58 (11)°. In the crystal, the benzohydrazide and water molecules are linked by N—H...O, O—H...O , O—H...N and C—H...O hydrogen bonds into a three-dimensional network.