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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 6(68), p. m823-m823, 2012

DOI: 10.1107/s1600536812023069

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Hexa­kis­(dimethyl­formamide-κO)manganese(II) (dimethyl­formamide-κO)pentakis(­thio­cyanato­-κN)chromate(III)

Journal article published in 2012 by Valentyna V. Semenaka, Oksana V. Nesterova ORCID, Vladimir N. Kokozay ORCID, Irina V. Omelchenko ORCID, Oleg V. Shishkin
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The title compound, [Mn(C3H7NO)6][Cr(NCS)5(C3H7NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as starting materials. The crystal structure of the complex consists of an [Mn(dmf)6]2+ cation and a [Cr(NCS)5(dmf)]2− anion (dmf = dimethylformamide). The MnII and CrIII atoms show a slightly distorted octahedral MnO6 and CrN5O coordination geometries with adjacent angles in the range 85.29 (13)–95.96 (14)°.