Published in

Elsevier, Materials Letters, (130), p. 263-266

DOI: 10.1016/j.matlet.2014.05.121

Links

Tools

Export citation

Search in Google Scholar

Spray-drying synthesis of Na2FePO4F/carbon powders for lithium-ion batteries

Journal article published in 2014 by Magali Brisbois, Natacha Krins, Raphael P. Hermann, Audrey Schrijnemakers, Rudi Cloots, Bénédicte Vertruyen ORCID, Frédéric Boschini ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

Sodium iron fluorophosphate Na2FePO4F is a candidate positive electrode material for both lithium-ion batteries and sodium-ion batteries. We report the synthesis of Na2FePO4F/carbon powders by the simple and easily up-scalable technique of spray-drying. An aqueous solution containing citric acid as a carbon source was sprayed in a pilot-scale spray-dryer. Heat treatment at 600°C in argon for 12 hours was found appropriate to obtain single-phase Na2FePO4F; only 1.8% of Fe (III) were detected by iron-57 Mössbauer spectroscopy. When cycled against lithium, the discharge capacity reached 110 mAh g-1 at C/15 rate. (C) 2014 Elsevier B.V. All rights reserved. ; Peer reviewed