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American Association for the Advancement of Science, Science, 6381(359), 2018

DOI: 10.1126/science.aas8953

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Response to Comment on “Synthesis and characterization of the pentazolate anion cyclo -N 5 – in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl”

Journal article published in 2018 by Chao Jiang ORCID, Lei Zhang ORCID, Chengguo Sun ORCID, Chong Zhang ORCID, Chen Yang, Jun Chen ORCID, Bingcheng Hu ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Huang and Xu argue that the cyclo -N 5 – ion in (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl we described in our report is theoretically unfavorable and is instead protonated. Their conclusion is invalid, as they use an improper method to assess the proton transfer in a solid crystal structure. We present an in-depth experimental and theoretical analysis of (N 5 ) 6 (H 3 O) 3 (NH 4 ) 4 Cl that supports the results in the original paper.