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European Geosciences Union, Atmospheric Measurement Techniques, 1(11), p. 329-339, 2018

DOI: 10.5194/amt-11-329-2018

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Diode laser-based gas analyser for the simultaneous measurement of CO<sub>2</sub> and HF in volcanic plumes

Journal article published in 2018 by Antonio Chiarugi, Silvia Viciani ORCID, Francesco D'Amato ORCID, Mike Burton ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Abstract. A portable analyser is described for simultaneous detection of CO2 and HF emitted by volcanoes and fumaroles. The system is based on two fibre-coupled distributed feedback lasers and only one multipass cell, and provides the absolute concentration values of the two gases, without requiring a calibration procedure, at a maximum rate of 4 Hz. The spectrometer can operate both in a closed-cell configuration and in an open-cell set-up, with the latter mitigating problems associated with chemisorption of the HF molecule. The concept, practical realization and laboratory performance of the device are presented, together with results from a first test campaign measuring volcanic gases emitted from the crater of Vulcano, Italy. We obtained an in-field sensitivity of 320 ppb for CO2 and 20 ppb for HF at 2 s integration time.