American Association for the Advancement of Science, Science, 6424(363), p. 265-270, 2019
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A redox road to recovery Device longevity is a key issue for organic-inorganic perovskite solar cells. Encapsulation can limit degradation arising from reactions with oxygen and water, but light, electric-field, and thermal stresses can lead to metastable elemental lead and halide atom defects. Wang et al. show that for the lead-iodine system, the introduction of the rare earth europium ion pair Eu 3+ -Eu 2+ can shuttle electrons and recover lead and iodine ions (Pb 2+ and I − ). Devices incorporating this redox shuttle maintained more than 90% of their initial power conversion efficiencies under various aging conditions. Science , this issue p. 265