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Annual Reviews, Annual Review of Physical Chemistry, 1(67), p. 541-564, 2016

DOI: 10.1146/annurev-physchem-040215-112347

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Theory of Linear and Nonlinear Surface-Enhanced Vibrational Spectroscopies

Journal article published in 2015 by Dhabih V. Chulhai, Zhongwei Hu ORCID, Justin E. Moore, Xing Chen, Lasse Jensen
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The vibrational spectroscopy of molecules adsorbed on metal nanoparticles can be enhanced by many orders of magnitude so that the detection and identification of single molecules are possible. The enhancement of most linear and nonlinear vibrational spectroscopies has been demonstrated. In this review, we discuss theoretical approaches to understanding linear and nonlinear surface-enhanced vibrational spectroscopies. A unified description of enhancement mechanisms classified as either electromagnetic or chemical in nature is presented. Emphasis is placed on understanding the spectral changes necessary for interpretation of linear and nonlinear surface-enhanced vibrational spectroscopies.