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International Union of Crystallography, Acta Crystallographica Section E: Crystallographic Communications, 7(72), p. 1032-1036, 2016

DOI: 10.1107/s2056989016009853

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Crystal structure of diaquabis(7-diethylamino-3-formyl-2-oxo-2H-chromen-4-olato-κ2O3,O4)zinc(II) dimethyl sulfoxide disolvate

Journal article published in 2016 by Aaron B. Davis, Frank R. Fronczek ORCID, Karl J. Wallace
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The structure of the title coordination complex, [Zn(C14H14NO4)2(H2O)2]·2C2H6OS, shows that the ZnIIcation adopts an octahedral geometry and lies on an inversion center. Two organic ligands occupy the equatorial positions of the coordination sphere, forming a chelate ring motifviathe O atom on the formyl group and another O atom of the carbonyl group (a pseudo-β-diketone motif). Two water molecules occupy the remaining coordination sites of the ZnIIcation in the axial positions. The water molecules are each hydrogen bonded to a single dimethyl sulfoxide molecule that has been entrapped in the crystal lattice.