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American Association for the Advancement of Science, Science, 6286(352), p. 667-667, 2016

DOI: 10.1126/science.aaf1652

American Association for the Advancement of Science, Science, 6286(352), p. 667-667, 2016

DOI: 10.1126/science.aad8843

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Response to Comment on “Cycling Li-O 2 batteries via LiOH formation and decomposition”

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Lithium-oxygen (Li-O 2 ) batteries cycle reversibly with lithium iodide (LiI) additives in dimethoxyethane (DME) to form lithium hydroxide (LiOH). Viswanathan et al. argue that because the standard redox potential of the four-electron (e ) reaction, 4OH ↔ 2H 2 O + O 2 + 4 e , is at 3.34 V versus Li + /Li, LiOH cannot be removed by the triiodide ion (I 3 ). However, under nonaqueous conditions, this reaction will occur at a different potential. LiOH also reacts chemically with I 3 to form IO 3 , further studies being required to determine the relative rates of the two reactions on electrochemical charge.