Published in
Royal Society of Chemistry, Chemical Science, 8(7), p. 5052-5058, 2016
DOI: 10.1039/c6sc01520d
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Iminoboronates are efficient intermediates for selective, rapid and reversible N-terminal cysteine functionalisation
Journal article published in 2016 by
Hélio Faustino 
,
Maria J. S. A. Silva ,
Luís F. Veiros ,
Gonçalo J. L. Bernardes ,
Pedro M. P. Gois
,
Maria J. S. A. Silva ,
Luís F. Veiros ,
Gonçalo J. L. Bernardes ,
Pedro M. P. Gois
This paper is made freely available by the publisher.
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Abstract
Formyl benzeno boronic acids rapidly and selectively react withN-terminal cysteines to yield a reversible boronated thiazolidine that may be used in the interactive orthogonal modification of peptides.