The synthesis of new metalated diporphyrinylamines is described. The electronic ≪communication≫ through the amino function linking the two porphyrins was clearly demonstrated by electronic spectroscopy. In addition, intramolecular magnetic interactions were measured between two copper(II) ions located in the two linked porphyrins. Compared to the reported value ([Formula: see text] -2 K) for Osuka’s triply fused bis-copper(II) porphyrin dimer, a relatively high antiferromagnetic coupling constant was determined in our compound ([Formula: see text] = -11 K).