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Royal Society of Chemistry, RSC Advances, 59(6), p. 54263-54269, 2016

DOI: 10.1039/c6ra12274d

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Reaction of sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl) benzenesulfonate with ethylenediamine on Cu(ii) and Ni(ii) centres: efficient Cu(ii) homogeneous catalysts for cyanosilylation of aldehydes

Journal article published in 2016 by Abdallah G. Mahmoud ORCID, Kamran T. Mahmudov, M. Fátima C. Guedes da Silva ORCID, Armando J. L. Pombeiro
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Reaction of sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl)benzenesulfonate with ethylenediamine on Cu(ii) and Ni(ii) centres lead to variety of metal complexes which effectively catalyse the cyanosilylation of aldehydes with trimethylsilyl cyanide.