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American Association for the Advancement of Science, Science, 6302(353), 2016

DOI: 10.1126/science.aaf3762

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Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Bonding to berkelium A geographical theme prevailed in the recent naming of the heaviest chemical elements. The choices brought to mind berkelium (Bk) and californium (Cf), the names chosen for elements 97 and 98 over half a century ago. Silver et al. now revisit the chemistry of Bk, which has proven fiercely challenging to study over the years on account of its vigorous radioactive decay. Synthetic crystallized Bk borate and dipicolinate compounds structurally resembled Cf analogs in the solid state but manifested distinct electronic and magnetic characteristics stemming from spin-orbit coupling effects. Science , this issue p. 888