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Published in

American Institute of Physics, The Journal of Chemical Physics, 18(145), p. 181101

DOI: 10.1063/1.4967405

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Communication: Dopant-induced solvation of alkalis in liquid helium nanodroplets

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Alkali metal atoms and small alkali clusters are classic heliophobes and when in contact with liquid helium they reside in a dimple on the surface. Here we show that alkalis can be induced to submerge into liquid helium when a highly polarizable co-solute, C60, is added to a helium nanodroplet. Evidence is presented that shows that all sodium clusters, and probably single Na atoms, enter the helium droplet in the presence of C60. Even clusters of cesium, an extreme heliophobe, dissolve in liquid helium when C60 is added. The sole exception is atomic Cs, which remains at the surface.