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A novel highly luminescent LnMOF film : a convenient sensor for Hg 2+ detecting

Published in 2013 by Ym Zhu, Ch Zeng, Ts Chu, Hm Wang, Yy Yang, Yx Tong, Cy Su, Wt Wong
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Preprint: policy unknown
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Abstract

A highly luminescent LnMOF {[Eu2(bqdc)3(H 2O)(DMF)3]·0.5DMF·H2O} n (1, bqdc = 2,2′-biquinoline-4,4′-dicarboxylate) was designed and synthesized. It was characterized by single crystal X-ray diffraction, PXRD, TGA, EA and FT-IR. A new strategy for preparing mechanically robust MOF thin films was developed by electrodeposition in combination with subsequent solvothermal synthesis. A portable sensor device prototype consisting of a film of 1 was conveniently fabricated by using this new strategy and this sensor device exhibits a highly selective response to Hg2+. Its luminescence quenching can be distinguished clearly with the naked eye when illuminated by a handy UV banknote detector. The diffusion kinetics of Hg 2+ into the LnMOF film is first proposed. ; Department of Applied Biology and Chemical Technology