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Wiley, ChemistrySelect, 4(2), p. 1573-1577, 2017

DOI: 10.1002/slct.201601864

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Melamine and spermine mediated supramolecular self-assembly of octaphosphonate tetraphenyl porphyrin

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

We demonstrate the supramolecular self-assembly of {porphyrin-5,10,15,20-tetrayltetrakis[(benzene-5,1,3-triyl)bis (methylene)]}octakis(phosphonic acid) 1 in the presence of melamine and spermine. The morphology of 1 in the presence of melamine and spermine was different, indicated that change in analytes could be used to control nanostructures. UV-vis and fluorescence spectroscopic methods were employed to investigate aggregation mode. The self-assembled nanostructure was confirmed by SEM imaging and XRD measurements.