Published in
Beilstein-Institut, Beilstein Journal of Organic Chemistry, (5), 2009
DOI: 10.3762/bjoc.5.56
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Continuous flow enantioselective arylation of aldehydes with ArZnEt using triarylboroxins as the ultimate source of aryl groups
Journal article published in 2009 by
Julien Rolland,
Xacobe C. Cambeiro,
Carles Rodríguez-Escrich,
Miquel A. Pericàs 
This paper is made freely available by the publisher.
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Abstract
A continuous flow system for the synthesis of enantioenriched diarylmethanols from aldehydes is described. The system uses an amino alcohol-functionalized polystyrene resin as the catalyst, and the arylating agent is conveniently prepared by transmetallation of triarylboroxins with diethylzinc.