The University of Chicago Press, The Journal of Geology, 6(109), p. 737-753, 2001
DOI: 10.1086/323192
Full text: Unavailable
The episodic variation of the seawater 87 Sr/ 86 Sr ratio has been attributed to either variations in the Sr flux or the Sr-isotopic composition of the riverine-dissolved load derived from weathering of the continental crust. The discovery that Himalayan rivers are characterized by high concentrations of dissolved Sr concentrations with high 87Sr/86Sr ratios has raised the possibility that collisional orogens play a critical role in moderating the variations in seawater 87 Sr/ 86 Sr ratios. Here we describe Himalayan carbonates and calc-silicates from Garhwal, the headwaters of the Ganges, with extreme 87 Sr/ 86 Sr ratios (>1.0). Elevated Sr-isotope ratios result from exchange with Rb-rich silicate material during both Himalayan and pre-Himalayan metamorphic episodes, and the carbonates contribute a significant fraction to the Ganges 87 Sr flux. Particularly elevated 87 Sr/ 86 Sr ratios are found in calc-silicates from the Deoban Formation of the Lesser Himalaya. A detailed traverse of shales and calc-silicates from this unit confirms that carbonate horizons have increased 87 Sr/ 86 Sr ratios as a result of isotopic exchange over length scales of 10-30 cm. We conclude that metamorphism of carbonates may cause elevation of their 87 Sr/ 86 Sr ratios and that uplift of metamorphosed carbonates may be a consequence of collisional orogens, which contributes to the elevation of seawater 87 Sr/ 86 Sr ratios.