We present the results of high-resolution (1-0.4A) optical spectroscopy of a sample of very low-mass stars. These data are used to examine the kinematics of the stars at the bottom of the hydrogen-burning main sequence. No evidence is found for a significant difference between the kinematics of the stars in our sample with I-K > 3.5 (MBol > 12.8) and those of more massive M-dwarfs (MBol = 7-10). A spectral atlas at high (0.4A) resolution for M8-M9+ stars is provided, and the equivalent widths of Cs I, Rb I and H$α$ lines present in our spectra are examined. We analyse our data to search for the presence of rapid rotation, and find that the brown dwarf LP944-20 is a member of the class of ``inactive, rapid rotators''. Such objects seem to be common at and below the hydrogen burning main sequence. It seems that in low-mass/low-temperature dwarf objects either the mechanism which heats the chromosphere, or the mechanism which generates magnetic fields, is greatly supressed.