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American Chemical Society, Organic Letters, 19(10), p. 4279-4282, 2008

DOI: 10.1021/ol801676u

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Copper + Nickel-in-Charcoal (Cu-Ni/C): A Bimetallic, Heterogeneous Catalyst for Cross-Couplings

Journal article published in 2008 by Bruce H. Lipshutz, Danielle M. Nihan, Ekaterina Vinogradova ORCID, Benjamin R. Taft, Žarko V. Bošković
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A new heterogeneous catalyst composed of copper and nickel oxide particles supported within charcoal has been developed. It catalyzes cross-couplings that traditionally use palladium, nickel, or copper, including Suzuki-Miyaura reactions, Buchwald-Hartwig aminations, vinylalane alkylations, etherifications of aryl halides, aryl halide reductions, asymmetric conjugate reductions of activated olefins, and azide-alkyne "click" reactions.